We introduce a novel discriminative learning approach to image set classification by modeling the image set with its natural second order statistic, i.e., covariance matrix. Since nonsingular covariance matrices, a.k.a. symmetric positive definite (SPD) matrices, lie on a Riemannian manifold, classical learning algorithms cannot be directly utilized to classify points on the manifold. By exploring an efficient metric for the SPD matrices, i.e., Log-Euclidean Distance (LED), we derive a kernel function that explicitly maps the covariance matrix from the Riemannian manifold to a Euclidean space. With this explicit mapping, any learning method devoted to vector space can be exploited in either linear or kernel formulation. Linear Discriminant Analysis (LDA) and Partial Least Squares (PLS) are considered in this paper for their feasibility for our specific problem. The proposed method is evaluated on two tasks: face recognition and object categorization. Extensive experimental results show not only the superiority of our method over state-of-the-art ones in both accuracy and efficiency, but also its stability to two real challenges: noisy set data and varying set size.